Rare Oxidation-State Combinations and Unusual Structural Motifs in Hexanuclear Mn Complexes Using 2-Pyridyloximate Ligands

descriptionPublicationkeyboard_double_arrow_right Article 14 Apr 2010 Cyprus, Spain English Publisher:American Chemical Society (ACS)Journal:Inorganic Chemistry, volume 49, pages 4,388-4,390 (issn: 0020-1669, eissn: 1520-510X,

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Authors: Stoumpos, Constantinos C.; Inglis, R.; Roubeau, O.; Sartzi, H.; Kitos, Alexandros A.; Milios, Constantinos J.; Aromí, Guillem; +15 Authors

doi: 10.1021/ic100089y

pmid: 20392125

handle: 10261/53754

Rare Oxidation-State Combinations and Unusual Structural Motifs in Hexanuclear Mn Complexes Using 2-Pyridyloximate Ligands

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Abstract

The use of phenyl-2-pyridyl ketone oxime and di-2-pyridyl ketone oxime in Mn chemistry has led to hexanuclear clusters with unprecedented (Mn(II)(4)Mn(III)Mn(IV)) or extremely rare (Mn(II)Mn(III)(5) and Mn(II)(3)Mn(III)(3)) metal oxidation-state combinations and uncommon structural motifs.

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