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Nature Nanotechnology
Article . 2011 . Peer-reviewed
License: Springer TDM
Data sources: Crossref
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Long-range electron tunnelling in oligo-porphyrin molecular wires

Authors: Sedghi, Gita; Garcia-Suarez, Victor M.; Esdaile, Louisa J.; Anderson, Harry L.; Lambert, Colin J.; Martin, Santiago; Bethell, Donald; +5 Authors

Long-range electron tunnelling in oligo-porphyrin molecular wires

Abstract

Short chains of porphyrin molecules can mediate electron transport over distances as long as 5-10 nm with low attenuation. This means that porphyrin-based molecular wires could be useful in nanoelectronic and photovoltaic devices, but the mechanisms responsible for charge transport in single oligo-porphyrin wires have not yet been established. Here, based on electrical measurements of single-molecule junctions, we show that the conductance of the oligo-porphyrin wires has a strong dependence on temperature, and a weak dependence on the length of the wire. Although it is widely accepted that such behaviour is a signature of a thermally assisted incoherent (hopping) mechanism, density functional theory calculations and an accompanying analytical model strongly suggest that the observed temperature and length dependence is consistent with phase-coherent tunnelling through the whole molecular junction.

Country
United Kingdom
Keywords

Models, Molecular, Porphyrins, Nanowires, Electric Conductivity, Temperature, 500, 530, Electron Transport, Models, Chemical, Nanotechnology

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
views
OpenAIRE UsageCountsViews provided by UsageCounts
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326
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