The integration of bioenergy and carbon capture and storage (BECCS) presents a great opportunity for power production with global negative CO2 emissions. This work explores a novel synergetic system that integrates membranes, partial biomass oxycombustion and the calcium looping (CaL) process. Polymeric membranes generate oxygen-enriched air (OEA) with an O2 concentration of 40%v/v, which is used for partial oxycombustion of biomass waste. The CO2-enriched flue gas evolves from the waste-to-energy plant to the CaL unit, where CO2 concentration is increased up to 90-95%v/v, ready for purification and sequestration. Compared to only oxycombustion systems, the proposed concept presents fewer technological challenges in retrofitting boilers to waste-to-energy plants. Moreover, this new approach is highly efficient as integrating membranes to produce OEA instead of cryogenic distillation systems significantly reduces energy consumption. A novel integration concept is modelled to evaluate the whole process efficiency and the effect of key parameters on the system performance, such as the temperature of the reactors, the membrane surface area, and the partial oxy-combustion degree. The results show that the novel system has an energy consumption associated with CO2 capture below 4 MJ/kg CO2 (a 31% lower than that for a conventional CaL process), with a higher CO2 capture efficiency than oxycombustion and the CaL process separately. On the other hand, the economic analysis shows a higher CO2 capture cost for the novel configuration than for the typical CaL configuration due to the additional investment cost of the membrane system. Improvements in membrane performance, mainly by increasing its permeance and diminishing the required surface area, would significantly reduce the economic cost of this novel integration. Using membranes with permeance over 400 GPU would boost the competitiveness of the system.

Este ítem es la versión preprint del artículo. Se puede consultar la versión final aquí https://doi.org/10.1016/j.jclepro.2023.136776

Junta de Andalucia