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Composición isotópica del Pb en sedimentos de llanura de inundación en diversos ambientes antropogénicos

Authors: Adánez Sanjuán, Paula; Flem, Belinda; Llamas Borrajo, Juan Francisco;

Composición isotópica del Pb en sedimentos de llanura de inundación en diversos ambientes antropogénicos

Abstract

Los metales en los depósitos de llanuras de inundación pueden tener su origen tanto en fuentes naturales como antropogénicas y su movilidad depende de su origen así como de las condiciones en las que se encuentran. El objetivo de este trabajo es caracterizar la influencia antropogénica sobre ellos, mediante el estudio de los contenidos de Pb, así como de los ratios isotópicos de este elemento. Se han analizado tanto los contenidos totales en Pb, U y Th (ICP-MS + INAA), como los ratios de los isótopos: 206 Pb, 207 Pb y 208 Pb (ICP-SFMS). Se han seleccionado 16 perfiles de sedimentos de llanuras de inundación en diversas cuencas fluviales a lo largo de la Península Ibérica. Cada uno de estos perfiles tiene unas características concretas, bien por los usos del suelo (actividad antropogénica desarrollada en el área donde se encuentran), bien por las litologías que aportan el material a estos sedimentos. En todos los perfiles se espera algún tipo de influencia antropogénica. Se ha comprobado que la actividad antropogénica se refleja en algunos de estos sedimentos de llanura de inundación, ya que muchos de ellos muestran una variación de los contenidos totales de Pb, que coincide con cambios en los ratios isotópicos. Por lo general, un aumento en los contenidos de Pb en el perfil coincide con una firma isotópica menos radiogénica (ratios 206 Pb/207 Pb más bajos), mientras que menores contenidos presentan firmas más radiogénicas. En las zonas urbanas estos cambios son más evidentes, mientras que en zonas afectadas por actividades mineras las variaciones son más tenues. RESUMEN Metals in overbank deposits can have their origin in natural as well as in anthropogenic sources and their mobility depends on their origin and the way they are associated to sediments. The objective of this work is to characterize the anthropogenic influence over these deposits through the study of Pb contents as well as Pb isotopic ratios. The elements Pb, U and Th have been analyzed (ICP-MS + INAA) and the isotopic ratios of 206 Pb, 207 Pb y 208 Pb (ICP-SFMS). Sixteen overbank profiles have been selected in several basins along the Iberian Peninsula. Each of the profiles have specific characteristics, due to the land use (anthropogenic activity developed in the area surrounding the sampling location), as well as the lithologies that supply material to the sediments. It is expected that all the profiles present some kind of anthropogenic influence due to mining, industrial, urban or agricultural activities. Two profiles were sampled in areas where population is scarce and no significant impact is expected. It has been proven that the anthropogenic activity is reflected in some of the overbank profiles, since they show a variation in the Pb contents, which agrees with the isotopic ratios shifts. In general, profiles show a shift in the 206 Pb/207 Pb ratio, closely following the shift in lead concentrations. These changes are more relevant in urban areas, while in mining areas, changes are weaker.

Congreso Nacional de Geoquímica (12º. 2017. Linares, Jaén). Congreso Ibérico de Geoquímica (11º. 2017. Linares, Jaén)

Instituto Geológico y Minero de España, España

Country
Spain
Keywords

sedimento, composición, Sedimento, Isótopo, plomo, Geología, Química, isótopo

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selected citations
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This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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