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Voltage-driven motion of nitrogen ions: a new paradigm for magneto-ionics

Authors: Julius de Rojas; Alberto Quintana; Aitor Lopeandía; Joaquín Salguero; Beatriz Muñiz; Fatima Ibrahim; Mairbek Chshiev; +12 Authors

Voltage-driven motion of nitrogen ions: a new paradigm for magneto-ionics

Abstract

Abstract Magneto-ionics, understood as voltage-driven ion transport in magnetic materials, has largely relied on controlled migration of oxygen ions. Here, we demonstrate room-temperature voltage-driven nitrogen transport ( i.e ., nitrogen magneto-ionics) by electrolyte-gating of a CoN film. Nitrogen magneto-ionics in CoN is compared to oxygen magneto-ionics in Co 3 O 4 . Both materials are nanocrystalline (face-centered cubic structure) and show reversible voltage-driven ON-OFF ferromagnetism. In contrast to oxygen, nitrogen transport occurs uniformly creating a plane-wave-like migration front, without assistance of diffusion channels. Remarkably, nitrogen magneto-ionics requires lower threshold voltages and exhibits enhanced rates and cyclability. This is due to the lower activation energy for ion diffusion and the lower electronegativity of nitrogen compared to oxygen. These results may open new avenues in applications such as brain-inspired computing or iontronics in general.

Countries
Germany, United States, France, Spain
Keywords

positron annihilation lifetime spectroscopy, [SPI.NANO] Engineering Sciences [physics]/Micro and nanotechnologies/Microelectronics, Science, Q, positron annihilation spectroscopy, Materials Engineering, 530, nitrogen, [PHYS.COND.CM-MS] Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], Article, Co, Engineering, Surfaces, interfaces and thin films, Magnetic properties and materials, Chemical Sciences, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], magneto-ionics, [SPI.NANO]Engineering Sciences [physics]/Micro and nanotechnologies/Microelectronics, defetcs

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selected citations
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This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
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