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Orpiment (α-As2S3) under compression reports a strong change in the coordination of As atoms at 25 GPa, which can be ascribed to an isostructural phase transition. These changes are consistent with the formation of metavalent bonds in orpiment.
Raman scattering, High-pressure, mineral orpiment, FOS: Physical sciences, metavalent or resonant bonding, Electronic band structure, group-15 sesquichalcogenides, Metavalent bonding, Condensed Matter - Materials Science, ab initio calculations, Materials Science (cond-mat.mtrl-sci), Orpiment, X-ray diffraction, High pressure, x-ray diffraction, FISICA APLICADA, electronic band structure, Arsenic sulfide crystals, Ab initio calculations
Raman scattering, High-pressure, mineral orpiment, FOS: Physical sciences, metavalent or resonant bonding, Electronic band structure, group-15 sesquichalcogenides, Metavalent bonding, Condensed Matter - Materials Science, ab initio calculations, Materials Science (cond-mat.mtrl-sci), Orpiment, X-ray diffraction, High pressure, x-ray diffraction, FISICA APLICADA, electronic band structure, Arsenic sulfide crystals, Ab initio calculations
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