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Descriptores moleculares de la repelencia al agua en suelos afectados por incendios forestales. Uso de herramientas quimiométricas

Authors: Jiménez Morillo, N. T.; Almendros Martín, Gonzalo; Rosa Arranz, José M. de la; Jordán, A.; Zavala, Lorena M.; González-Vila, Francisco Javier; González-Pérez, José Antonio;

Descriptores moleculares de la repelencia al agua en suelos afectados por incendios forestales. Uso de herramientas quimiométricas

Abstract

[ES]: En este trabajo se evalúa la idoneidad de la combinación de técnicas de pirólisis analítica (Py-GC-MS) y herramientas quimio-métricas para obtener marcadores moleculares subrogados a la repelencia al agua en suelos afectados por un incendio forestal. Para ello, se estudiaron muestras de suelos completos (< 2 mm) en áreas forestales quemadas y no quemadas bajo Quercus suber (Parque Nacional de Doñana) así como 6 fracciones de distinto tamaño de partícula (1–2, 0.5–1, 0.25–0.5, 0.1–0.25, 0.05–0.1 y < 0.05 mm). Se observa que la repelencia al agua en los distintos suelos puede predecirse con precisión (P < 0.05) a partir de las abundancias de los compuestos orgánicos liberados por pirólisis. Por otro lado, pudo establecerse que los compuestos de pirólisis significativamente relacionados con la repelencia al agua eran diferentes en los suelos según hubieran sido afectados por el fuego o no. En las muestras tomadas en áreas no quemadas, la repelencia al agua estuvo principalmente asociada a la presencia de compuestos derivados de lignina, proteínas, carbohidratos y ácidos grasos. Por el contrario, en las muestras de suelo de las áreas quemadas, la repelencia al agua se correlacionó significativamente con la presencia de materia orgánica con predominio de estructuras alquílicas y aromáticas, y baja proporción de compuestos con grupos oxigenados.

[EN]: The combination of analytical pyrolysis (Py-GC-MS) and chemometric tools in obtaining molecular markers surrogated to soil water repellency of fire-affected forest soils is studied. Bulk (<2 mm) burnt and unburnt soil samples under Quercus suber cover (Doñana National Park) were collected, and up to 6 particle size fractions (1–2, 0.5–1, 0.25–0.5, 0.1–0.25, 0.05–0.1 and <0.05 mm) were isolated and analysed. It is observed that the levels of soil water repellency can be accurately predicted from the relative proportions of organic compounds released by pyrolysis. On the other hand, it was found that the pyrolysis compounds significantly related to water repellency were different depending on whether the soils had been affected by the fire, or not: In samples from unburnt areas, soil water repellency was associated mainly to the presence of lignin-derived compounds, carbo-hydrates, proteins and fatty acids. By contrast, in fire-affected forest soils, the high water repellency levels were associated with an organic matter consisting mainly of alkyl and aromatic structures, and less proportions of oxygen-containing compounds

4 páginas.-- 2 figuras.-- 8 referencias.-- Póster presentado en el VIII Congreso Ibérico de las Ciencias del Suelo. VIII Congresso Ibérico de Ciências do Solo. DONOSTIA-SAN SEBASTIÁN. 20 - 22 junio 2018..-- El documento completo se encuentra para su descarga en http://www.cics2018.com/libro-de-abstracts/

Trabajo parcialmente financiado por los proyectos INTERCARBON (CGL2016-78937-R) y COSEPROM (CGL2013-43845-P). Reconocimiento a D. Monis y A. Carmona por su inestimable ayuda duran-te la pirólisis analítica.

Peer Reviewed

Keywords

Prólisis analítica, Incendios forestales, Quimiometría, Van Krevelen, Hidrofobicidad

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
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