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Abstract The fundamental 28SiH+ ion has been characterized in a collaborative work, utilizing a hollow-cathode discharge laser spectrometer and a cryogenic ion trap spectrometer. Twenty-three vibration–rotation transitions around 4.75 μm have been detected with high accuracy. This has facilitated the first direct measurement of the pure rotational transition J = 1 ← 0 at 453056.3632(4) MHz in the trap spectrometer. The measured and accurately predicted transitions enable the search for this ion in space with IR and sub-mm telescopes.
Methods: laboratory: molecular, Molecular data, laboratory: molecular [Methods], Techniques: spectroscopic, FOS: Physical sciences, Astrophysics - Astrophysics of Galaxies, ISM: molecules, spectroscopic [Techniques], Astrophysics of Galaxies (astro-ph.GA), molecules [ISM]
Methods: laboratory: molecular, Molecular data, laboratory: molecular [Methods], Techniques: spectroscopic, FOS: Physical sciences, Astrophysics - Astrophysics of Galaxies, ISM: molecules, spectroscopic [Techniques], Astrophysics of Galaxies (astro-ph.GA), molecules [ISM]
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