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Lattice damage in 9-MeV-carbon irradiated diamond and its recovery after annealing

Authors: F. Agulló-Rueda; N. Gordillo; M.D. Ynsa; A. Maira; J. Cañas; M.A. Ramos;

Lattice damage in 9-MeV-carbon irradiated diamond and its recovery after annealing

Abstract

We have studied the radiation damage in diamond as a function of layer depth upon self-ion implantation with 9-MeV carbon ions and its recovery after annealing at 1000°C. Raman and photoluminescence spectra show substantial damage of the lattice, namely, amorphization, neutral vacancies, and interstitial defects. Damage is maximum in the stopping layer at a depth of 4 μm. After annealing there is some recovery of the lattice, but the residual damage increases with fluence, up to about 2E16 ions/cm2. At this fluence the stopping layer becomes highly disordered and does not heal with annealing. Surprisingly, for higher fluence values, of about 5E16 ions/cm2, there is almost no residual damage. After full amorphization is reached, the layers appear to recrystallize by solid phase epitaxy (SPE), using the pristine diamond layers underneath as a template. These results prove that graphitization of diamond after annealing can be avoided in deeply buried layers, implanted at fluences much higher than expected. High fluences, in fact, can lead to high quality diamond layers. If SPE can be confirmed, it would have a great interest for diamond device applications, as it allows for higher doping levels.

Country
Spain
Keywords

Nitrogen, Física, Recrystallization, Solid phase epitaxy, Carbon, Amorphization, Annealing, Vapor Deposition, Ion irradiation, Raman spectroscopy, Diamond, Vacancies

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selected citations
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This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
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