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Lignocellulosic wastes and by-products containing lignin are now available in large amounts from forestry and industrial activities, and could be promising organic materials for the biosorption of pesticides by soils in order to reduce point-source pollution. Adding these materials to soil requires understanding the process of pesticide sorption-desorption by wood-soils, as sorption capacity could increase, with changes in pesticide bioavailability and final fate. The objective of this work was to study the effect that pine and oak wood added to soils had on the sorption/desorption of the pesticides linuron, alachlor, and metalaxyl. Experiments were conducted with two sandy loam and sandy clay soils each amended with two wood doses (5% and 50%) after different incubation times (0, 5 and 12 months). A low wood dose (5%) had no significant impact on the sorption (Kf) of alachlor, but Kf increased for linuron (up to 5.4-1.7 times) and metalaxyl (up to 4.4 and 8.6 times) in all wood-soil systems. The results were not significantly different after different incubation times. The desorption results indicated that wood decreases the sorption irreversibility of alachlor, and increases that of linuron and metalaxyl, with a varying effect of the wood-soil incubation time. The addition of a high wood dose to soil (50%) was more significant for increasing the sorption of all the pesticides, and the sorbed amounts remaining after desorption (>49% for linuron, >33% for alachlor and >6% for metalaxyl), although there was no apparent discrimination between the two types of woods. The role of the nature of the organic carbón (Koc values) for sorption was evidenced for alachlor and metalaxyl, but not for linuron. These outcomes are of interest for extending wood application to soil as a barrier for avoiding environmental risk by point-source pollution due to the use and management of pesticides in farming systems.
Bioavailability, Alachor, Metalaxyl, Soil, Acetamides, Soil Pollutants, Toxicology and Mutagenesis, Linuron, Pesticides, Alanine, Environmental and Occupational Health, Pollution, Wood, Pine, Health, Oak, Alachlor, Soils, Sorption, Desorption, Public Health, Adsorption, Alachlor; Bioavailability; Desorption; Linuron; Metalaxyl; Oak; Pine; Soils; Sorption; Wood; Acetamides; Adsorption; Alanine; Linuron; Pesticides; Soil Pollutants; Soil; Wood; Pollution; Public Health, Environmental and Occupational Health; Health, Toxicology and Mutagenesis
Bioavailability, Alachor, Metalaxyl, Soil, Acetamides, Soil Pollutants, Toxicology and Mutagenesis, Linuron, Pesticides, Alanine, Environmental and Occupational Health, Pollution, Wood, Pine, Health, Oak, Alachlor, Soils, Sorption, Desorption, Public Health, Adsorption, Alachlor; Bioavailability; Desorption; Linuron; Metalaxyl; Oak; Pine; Soils; Sorption; Wood; Acetamides; Adsorption; Alanine; Linuron; Pesticides; Soil Pollutants; Soil; Wood; Pollution; Public Health, Environmental and Occupational Health; Health, Toxicology and Mutagenesis
citations This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically). | 17 | |
popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network. | Top 10% | |
influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically). | Average | |
impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network. | Top 10% |
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