Crystal structure of (E)-1-{[(3,5-dimethylphenyl)imino]methyl}naphthalen-2-ol

descriptionPublicationkeyboard_double_arrow_right Article 20 Jun 2015 Spain Publisher:International Union of Crystallography (IUCr)Journal:Acta Crystallographica Section E Crystallographic Communications, volume 71, pages o496-o497 (eissn: 2056-9890,

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Authors: Abu-Dief, Ahmed Mohamed; Said Mohammed Abdelbaky, Mohammed; García-Granda, Santiago;

doi: 10.1107/s2056989015011548

pmid: 26279928

pmc: PMC4518976

handle: 10651/39874 , 10261/137399

Crystal structure of (E)-1-{[(3,5-dimethylphenyl)imino]methyl}naphthalen-2-ol

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Abstract

The title compound, C19H17NO, has anEconformation about the N=C bond. The molecule is relatively planar, with the benzene ring and naphthalene ring plane being inclined to one another by 4.28 (10)°. There is an intramolecular O—H...N hydrogen bond generating anS(6) ring motif. In the crystal, molecules are linkedviaC—H...O hydrogen bonds, forming chains propagating along [100]. Within the chains there are π–π interactions involving the benzene ring and the naphthalene ring system of an adjacent molecule [inter-centroid distance = 3.6405 (14) Å].

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Spain

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Keywords

Hydrogen bonding, crystal structure, Crystallography, hydrogen bonding, Data Reports, Schiff base, QD901-999, imino, naphthalen-2-ol, Crystal structures, Naphthalen-2-ol, Imino

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