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Diffusion Fundamentals
Article . 2005 . Peer-reviewed
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Solid-state diffusion and NMR

Authors: Heitjans, Paul; Indris, Sylvio; Wilkening, Martin;

Solid-state diffusion and NMR

Abstract

Diffusion in solids, which requires the presence of crystal defects or disorder, has both microscopic and macroscopic aspects. Nuclear magnetic resonance techniques provide access to microscopic diffusion parameters like atomic jump rates and activation energies as well as to the tracer diffusion coefficient for macroscopic transport. Microscopic NMR methods include spin-lattice relaxation spectroscopy of stable and beta-radioactive nuclei, spin-spin relaxation or linewidth and spin alignment decay measurements, whereas macroscopic NMR methods are represented by the techniques of static and pulsed field gradient NMR. We recall some basic principles of the mentioned techniques and review case studies for their application to various solids like glassy and crystalline aluminosilicates, nanocrystalline composites, an intercalation compound and a simple bcc metal. Taken together, jump rates in solids are covered over about 10 decades by the microscopic, and diffusion coefficients over 3 decades by the macroscopic NMR methods.

Country
Germany
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Keywords

diffusion, transport, nanocrystalline composites, ddc:530, aluminosilicates, Solid-state diffusion, Diffusion, Transport, PFG NMR, motional line narrowing, lithium, NMR spin-lattice relaxation, Dewey Decimal Classification::500 | Naturwissenschaften::530 | Physik, spin alignment, info:eu-repo/classification/ddc/530, SFG NMR, Konferenzschrift

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
31
Top 10%
Top 10%
Top 10%
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gold