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Dental Materials Journal
Article . 2003 . Peer-reviewed
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Real-time Monitoring of Apatite Deposition Using Electrochemical Quartz Crystal Microbalance

Authors: Seiji, Ban;

Real-time Monitoring of Apatite Deposition Using Electrochemical Quartz Crystal Microbalance

Abstract

The electrochemical deposition process of apatite was monitored in real-time using an electrochemical quartz crystal microbalance (EQCM). A piezoelectric quartz oscillator with titanium was fixed to a cell and connected to a frequency counter. The electrolyte temperature was maintained at 20, 37, and 60 degrees C and the direct current density was constant at 0.2, 0.5, 1.0, and 2.0 mA/cm2. The deposited amount derived from the frequency change increased as electrolyte temperature and current density increased. The critical times, which are the starting times of quick increases of deposition, decreased with them. The critical times observed in the present study, namely in situ, were much shorter than those obtained from real weight change reported in our previous report. The apparent activation energies of the electrochemical deposition of apatite under 1.0 and 2.0 mA/cm2 were about 36.1 and 31.9 kJ/mol, respectively. These results indicate that electro current loading may reduce the activation energy required for the deposition of calcium phosphates.

Related Organizations
Keywords

Titanium, Time Factors, Temperature, Signal Processing, Computer-Assisted, Quartz, Hydrogen-Ion Concentration, Vibration, Coated Materials, Biocompatible, Apatites, Electrochemistry, Adsorption

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
14
Average
Top 10%
Top 10%
gold