We consider smooth complete intersection Calabi-Yau 3-folds in minuscule Schubert varieties, and study their mirror symmetry by degenerating the ambient Schubert varieties to Hibi toric varieties. We list all possible Calabi-Yau 3-folds of this type up to deformation equivalences, and find a new example of smooth Calabi-Yau 3-folds of Picard number one; a complete intersection in a locally factorial Schubert variety ${\boldsymbolΣ}$ of the Cayley plane ${\mathbb{OP}}^2$. We calculate topological invariants and BPS numbers of this Calabi-Yau 3-fold and conjecture that it has a non-trivial Fourier-Mukai partner.