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Polymers
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Multiferroic Coupling of Ferromagnetic and Ferroelectric Particles through Elastic Polymers

Authors: Liudmila A. Makarova; Danil A. Isaev; Alexander S. Omelyanchik; Iuliia A. Alekhina; Matvey B. Isaenko; Valeria V. Rodionova; Yuriy L. Raikher; +1 Authors

Multiferroic Coupling of Ferromagnetic and Ferroelectric Particles through Elastic Polymers

Abstract

Multiferroics are materials that electrically polarize when subjected to a magnetic field and magnetize under the action of an electric field. In composites, the multiferroic effect is achieved by mixing of ferromagnetic (FM) and ferroelectric (FE) particles. The FM particles are prone to magnetostriction (field-induced deformation), whereas the FE particles display piezoelectricity (electrically polarize under mechanical stress). In solid composites, where the FM and FE grains are in tight contact, the combination of these effects directly leads to multiferroic behavior. In the present work, we considered the FM/FE composites with soft polymer bases, where the particles of alternative kinds are remote from one another. In these systems, the multiferroic coupling is different and more complicated in comparison with the solid ones as it is essentially mediated by an electromagnetically neutral matrix. When either of the fields, magnetic or electric, acts on the ‘akin’ particles (FM or FE) it causes their displacement and by that perturbs the particle elastic environments. The induced mechanical stresses spread over the matrix and inevitably affect the particles of an alternative kind. Therefore, magnetization causes an electric response (due to the piezoeffect in FE) whereas electric polarization might entail a magnetic response (due to the magnetostriction effect in FM). A numerical model accounting for the multiferroic behavior of a polymer composite of the above-described type is proposed and confirmed experimentally on a polymer-based dispersion of iron and lead zirconate micron-size particles.

Countries
Russian Federation, Italy
Keywords

MULTIFERROICS, FERROMAGNETIC PARTICLES, MAGNETOELECTRIC COMPOSITES, CRYSTALLOGRAPHY, MAGNETOSTRICTION, Elastic properties; Ferroelectric particles; Ferromagnetic particles; Magnetoelectric composite; Multiferroics, FERROELECTRICITY, FERROMAGNETICS, MULTIFERROIC BEHAVIOR, MAGNETOELECTRIC COMPOSITE, ELECTRIC FIELDS, Article, ELASTIC PROPERTIES, FERROELECTRIC PARTICLES, FERROMAGNETIC MATERIALS, ferromagnetic particles; ferroelectric particles; magnetoelectric composite; multiferroics; elastic properties, MATRIX, POLARIS, MECHANICAL STRESS

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
8
Top 10%
Average
Top 10%
Green
gold