This manuscript presents set-theoretical solutions to the Yang–Baxter equation within the framework of GE-algebras by constructing mappings that satisfy the braid condition and exploring the algebraic properties of GE-algebras. Detailed proofs and the use of left and right translation operators are provided to analyze these algebraic interactions, while an algorithm is introduced to automate the verification process, facilitating broader applications in quantum mechanics and mathematical physics. Additionally, the Yang–Baxter equation is applied to spin transformations in quantum mechanical spin-12 systems, with transformations like rotations and reflections modeled using GE-algebras. A Cayley table is used to represent the algebraic structure of these transformations, and the proposed algorithm ensures that these solutions are consistent with the Yang–Baxter equation, offering new insights into the role of GE-algebras in quantum spin systems.