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ASEAN Journal on Science and Technology for Development
Article . 2018 . Peer-reviewed
License: CC BY SA
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Influence of TESPT on Tensile and Tear Strengths of Vulcanized Silica-filled Natural Rubbe

Authors: A.K. NORIZAH; S. AZEMI;

Influence of TESPT on Tensile and Tear Strengths of Vulcanized Silica-filled Natural Rubbe

Abstract

The effectof coupling agent on tensile and tear strengthsof vulcanized NR filledwith 50 pphr of precipitated silica (VN3) was investgated. The amount of coupling agent was varied from 0,1,2,3,4,5 to 8 pphr. In the absence of coupling agent bis[3-(triethoxysilyl)propyl] tetrasulphide (TESPT), the tensile strengthof silica-fille vulcanized NR was lower than the tensile strengthof unfilledvulcanized NR. The enhancement in the tensile strengthwas achieved only when TESPT was incorporated into the rubber compound. The dependence of tensile strengthon the amount of TESPT showed a similar trend as the dependence of tensile strengthon the crosslink concentration. This might imply that varying the amount of TESPT was analogous to varying the crosslink concentration of the rubber network. The effct of TESPT on tearing energy was very strking in silica-filed vulcanized NR. Without Si69, the crack propagated in a steady(smooth) manner where the tearing energy increases with increasing testspeed. When TESPT was added into the silica mix, the crack propagated sideways from the intended tear path producing the so called knotty tearing. The tearing energy was about a factor of ten higher than that without coupling agent in particular at low tear rates regions. The results here indicated clearly that in silica-filledvulcanized NR, coupling agent was essential to induce the strengthanisotropy necessary for the occurrence of knotty tearing. The result also showed that TESPT also influencedthe amount of hysteresisin silica-filledvulcanized NR. Both tensile and tear strengths were affected by the hysteresi

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Keywords

Science (General), silane 69, Q1-390, TESPT, tensile strength, hysteresis, Coupling agent, tearing energy, T1-995, Technology (General)

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
5
Top 10%
Average
Average
gold