Abstract Study of three phase equilibrium has been seen from many literatures. Most research on modeling of asphaltene precipitation has remained in qualitative description stage. Even though quantitative calculation of asphaltene precipitation can be seen from some reports. However, quantitative calculation of asphaltene precipitation with three phase flash algorithm is unstable because gas-liquid-solid material balance equations is highly non-linear equations. In the light of general view that there are not heavy hydrocarbons with high molecular weight including asphalt in gas phase, technique of stable asphaltene precipitation calculation is put forward by the paper. The recommended technique in the paper separates gas-liquid-solid equilibrium into two parts: gas-liquid and liquid-solid equilibrium. Liquid phase is a bridge between gas and solid phase and solid precipitates always from liquid phase. Gas-liquid equilibrium is described through EOS and fugacity of asphaltene determined from gas-liquid equilibrium should be compared and accord with fugacity of pure solid phase of asphaltene. In this way, modeling of three phase equilibrium becomes easier and more stable. The validation of the model with experimental data is described also in the paper. Additionally, the paper puts forward gas-liqiud-asphaltene material balance equations which can be deduced from general three phase material balance equations and are not similar to them in forms.