The direct simulation Monte Carlo (DSMC) method has been used to calculate the molecular velocity and energy distributions of molecules striking a surface after traversing a shock layer in hypersonic transitional flow. The calculations were performed for a 1.6-m-diameter sphere at a nominal velocity for re-entry of 7.5 km/s over an altitude range of 130 to 90 km. Real gas effects and chemical reactions were included in the DSMC simulations. Results are presented for these conditions and the need for gas-surface interaction experiments is discussed.