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Kinetics of Slurry Phase Fischer-Tropsch Synthesis

Authors: Bukur, Dragomir B.; Froment, Gilbert F.; Olewski, Tomasz; Nowicki, Lech; Nayapati, Madhav;

Kinetics of Slurry Phase Fischer-Tropsch Synthesis

Abstract

This report covers the first year of this three-year research grant under the University Coal Research program. The overall objective of this project is to develop a comprehensive kinetic model for slurry phase Fischer-Tropsch synthesis on iron catalysts. This model will be validated with experimental data obtained in a stirred tank slurry reactor (STSR) over a wide range of process conditions. The model will be able to predict concentrations of all reactants and major product species (H{sup 2}O, CO{sub 2}, linear 1- and 2-olefins, and linear paraffins) as a function of reaction conditions in the STSR. During the reporting period we have completed one STSR test with precipitated iron catalyst obtained from Ruhrchemie AG (Oberhausen-Holten, Germany). This catalyst was initially in commercial fixed bed reactors at Sasol in South Africa. The catalyst was tested at 13 different sets of process conditions, and had experienced a moderate deactivation during the first 500 h of testing (decrease in conversion from 56% to 50% at baseline process conditions). The second STSR test has been initiated and after 270 h on stream, the catalyst was tested at 6 different sets of process conditions.

Country
United States
Related Organizations
Keywords

Isomerization, And Peat, Hydrocracking, Secondary Reactions, Iron, Testing, 12 Management Of Radioactive Wastes, Slurry Reactors, Alkenes, 21 Specific Nuclear Reactors And Associated Plants, Research Programs, Alkanes, Reaction Kinetics, Lignite, Fischer-Tropsch Synthesis, Flow Rate, And Non-Radioactive Wastes From Nuclear Facilities, Packed Beds, Catalysts, Computer Codes, Deactivation, Hydrocarbons, Minimization, Carbon, Molecular Weight, 01 Coal, Kinetics, Coal, Paraffin, Hydrogenation, Tanks, Forecasting

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
Average