
doi: 10.2172/7248905
The sequential simplex method has been used to estimate the extent of disproportionation of tetravalent plutonium in dilute acid. A method for simulating potentiometric titrations is proposed, and this method suggests that the stoichiometric end point and the inflection point may not always correspond in the potentiometric titration of plutonium. A possible characteristic equation for the nitrite-plutonium reaction is illustrated, and the method of proportional equations is extended to the iron-plutonium reaction.
Optimization, Radiochemistry, Equilibrium, Chemical Reactions, Elements, Plutonium, Actinides, 38 Radiation Chemistry, Transuranium Elements 400702* -- Radiochemistry & Nuclear Chemistry-- Properties Of Radioactive Materials, Metals, Oxidation, And Nuclear Chemistry, Reduction
Optimization, Radiochemistry, Equilibrium, Chemical Reactions, Elements, Plutonium, Actinides, 38 Radiation Chemistry, Transuranium Elements 400702* -- Radiochemistry & Nuclear Chemistry-- Properties Of Radioactive Materials, Metals, Oxidation, And Nuclear Chemistry, Reduction
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