The effect of chemical additives on the synthesis of ethanol
The effect of chemical additives on the synthesis of ethanol
The objective of this research is to elucidate the role of various chemical additives on ethanol synthesis over Rh- and Ni-based catalysts. Chemical additives used for this study will include S, P, Ag, Cu, Mn, and Na which have different electronegativities. The effect of additives on the surface state of the catalysts, heat of adsorption of reactant molecules, reaction intermediates, reaction pathways, reaction kinetics, and product distributions is/will be investigated by a series of experimental studies of NO adsorption, reaction probing, study state rate measurement, and transient kinetic study. A better understanding of the role of additive on the synthesis reaction may allow us to sue chemical additives to manipulate the catalytic properties of Rh- and Ni-based catalysts for producing high yields of ethanol from syngas. (VC)
- University System of Ohio United States
- University of North Texas System United States
- University of Akron United States
- Office of Scientific and Technical Information United States
Carbon Oxides, Thermodynamic Properties, Yields, Adsorption Heat, Catalytic Effects, Hydroxy Compounds, Synthesis, Enthalpy, Nickel, & Peat-- C1 Processes-- (1987-), Rhenium Compounds, Lignite, Nitrogen Compounds, Carbon Monoxide, Fluids, Catalysts, Infrared Spectrometers, Spectrometers, Organic Compounds, Silicon Compounds, Methanation, Chemical Reactions, Phosphorus, Oxides, Spectra, Elements, Transition Elements 010408* -- Coal, Metals, Specificity, Thermodynamics, Sorption, Nitrogen Oxides, Hydrogenation, Synthesis Gas, Reaction Intermediates, Gases, Platinum Metals, Oxygen Compounds, Transition Elements 090900* -- Biomass Fuels-- Processing-- (1990-), Silicon Oxides, Transition Element Compounds, And Peat, Silver, Infrared Spectra, Chemical Reaction Kinetics, Surface Properties, Nickel Compounds, Sulfides, Nitric Oxide, Ruthenium, Alkali Metals, 09 Biomass Fuels, Chemical Preparation, Reaction Kinetics, Rhodium, Manganese, Progress Report, Ethanol, Sodium, Additives, Hydrogen Sulfides, Conversion, Document Types, Hydrocarbons, Carbon Compounds, Measuring Instruments, Physical Properties, 01 Coal, Kinetics, Nonmetals, Alcohols, Sulfidation, Potassium, Desorption, Adsorption, Copper, Sulfur, Chalcogenides, Refractory Metal Compounds
Carbon Oxides, Thermodynamic Properties, Yields, Adsorption Heat, Catalytic Effects, Hydroxy Compounds, Synthesis, Enthalpy, Nickel, & Peat-- C1 Processes-- (1987-), Rhenium Compounds, Lignite, Nitrogen Compounds, Carbon Monoxide, Fluids, Catalysts, Infrared Spectrometers, Spectrometers, Organic Compounds, Silicon Compounds, Methanation, Chemical Reactions, Phosphorus, Oxides, Spectra, Elements, Transition Elements 010408* -- Coal, Metals, Specificity, Thermodynamics, Sorption, Nitrogen Oxides, Hydrogenation, Synthesis Gas, Reaction Intermediates, Gases, Platinum Metals, Oxygen Compounds, Transition Elements 090900* -- Biomass Fuels-- Processing-- (1990-), Silicon Oxides, Transition Element Compounds, And Peat, Silver, Infrared Spectra, Chemical Reaction Kinetics, Surface Properties, Nickel Compounds, Sulfides, Nitric Oxide, Ruthenium, Alkali Metals, 09 Biomass Fuels, Chemical Preparation, Reaction Kinetics, Rhodium, Manganese, Progress Report, Ethanol, Sodium, Additives, Hydrogen Sulfides, Conversion, Document Types, Hydrocarbons, Carbon Compounds, Measuring Instruments, Physical Properties, 01 Coal, Kinetics, Nonmetals, Alcohols, Sulfidation, Potassium, Desorption, Adsorption, Copper, Sulfur, Chalcogenides, Refractory Metal Compounds
selected citations These citations are derived from selected sources.This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).0 popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.Average influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).Average impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.Average
Citations provided by BIP!Popularity provided by BIP!