
doi: 10.2172/6468385
Experimental anion permeselective membranes were improved and characterized for use as separators in a chemical redox, power storage cell being developed at the NASA Lewis Research Center. The goal of minimal Fe/sup +3/ ion transfer was achieved for each candidate membrane system. Minimal membrane resistivity was demonstrated by reduction of film thickness using synthetic backing materials but usefulness of thin membranes was limited by the scarcity of compatible fabrics. The most durable and useful backing fabrics were modacrylics. One membrane, a copolymer of 4 vinylpyridine and vinyl benzylchloride was outstanding in overall electrochemical and physical properties. Long term (1000 hrs) membrane chemical and thermal durability in redox environment was shown by three candidate polymers and two membranes. The remainder had good durability at ambient temperature. Manufacturing capability was demonstrated for large scale production of membrane sheets 5.5 ft/sup 2/ in area for two candidate systems.
Direct Energy Converters, Anions, Polymers, Atomic Ions, Dimensions, Redox Fuel Cells, Fabrication, Ion Exchange Materials, Charged Particles, Electrochemistry, Mass Transfer, Regenerative Fuel Cells 300503* -- Fuel Cells-- Materials, Components, Ions, Membranes, Organic Polymers, Polyacrylates, Carboxylic Acid Salts, Organic Compounds, Electrical Properties, Electric Conductivity, Esters, Battery Separators, Physical Properties, & Auxiliaries, Ion Exchange, Iron Ions, Manufacturing, Chemistry, Electrochemical Cells, Organic Ion Exchangers, 30 Direct Energy Conversion, Methacrylates, Polyvinyls, Fuel Cells, Thickness
Direct Energy Converters, Anions, Polymers, Atomic Ions, Dimensions, Redox Fuel Cells, Fabrication, Ion Exchange Materials, Charged Particles, Electrochemistry, Mass Transfer, Regenerative Fuel Cells 300503* -- Fuel Cells-- Materials, Components, Ions, Membranes, Organic Polymers, Polyacrylates, Carboxylic Acid Salts, Organic Compounds, Electrical Properties, Electric Conductivity, Esters, Battery Separators, Physical Properties, & Auxiliaries, Ion Exchange, Iron Ions, Manufacturing, Chemistry, Electrochemical Cells, Organic Ion Exchangers, 30 Direct Energy Conversion, Methacrylates, Polyvinyls, Fuel Cells, Thickness
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