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Anion permselective membrane. [For redox fuel cells]

Authors: Alexander, S.S.; Hodgdon, R.B.;

Anion permselective membrane. [For redox fuel cells]

Abstract

Experimental anion permeselective membranes were improved and characterized for use as separators in a chemical redox, power storage cell being developed at the NASA Lewis Research Center. The goal of minimal Fe/sup +3/ ion transfer was achieved for each candidate membrane system. Minimal membrane resistivity was demonstrated by reduction of film thickness using synthetic backing materials but usefulness of thin membranes was limited by the scarcity of compatible fabrics. The most durable and useful backing fabrics were modacrylics. One membrane, a copolymer of 4 vinylpyridine and vinyl benzylchloride was outstanding in overall electrochemical and physical properties. Long term (1000 hrs) membrane chemical and thermal durability in redox environment was shown by three candidate polymers and two membranes. The remainder had good durability at ambient temperature. Manufacturing capability was demonstrated for large scale production of membrane sheets 5.5 ft/sup 2/ in area for two candidate systems.

Country
United States
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Keywords

Direct Energy Converters, Anions, Polymers, Atomic Ions, Dimensions, Redox Fuel Cells, Fabrication, Ion Exchange Materials, Charged Particles, Electrochemistry, Mass Transfer, Regenerative Fuel Cells 300503* -- Fuel Cells-- Materials, Components, Ions, Membranes, Organic Polymers, Polyacrylates, Carboxylic Acid Salts, Organic Compounds, Electrical Properties, Electric Conductivity, Esters, Battery Separators, Physical Properties, & Auxiliaries, Ion Exchange, Iron Ions, Manufacturing, Chemistry, Electrochemical Cells, Organic Ion Exchangers, 30 Direct Energy Conversion, Methacrylates, Polyvinyls, Fuel Cells, Thickness

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
2
Average
Top 10%
Average
Related to Research communities