
doi: 10.2172/4828675
Laboratory-scale tests on methods for recovering uranium and thorium from graphite-base reactor fuel elements are reported. The 90% HNO/sub 3/ process, which involves simultaneous disintegration and leaching in 21 M HNO/sub 3/, is applicable to all fuel elenments which do not contain coated fuel particles. Leaching of irradiated (0.001% burnup) fuels containing 3 and 12% uranlum recovered approximates 99.3 and 99.9%, respectively, of the uranium in two 4-hr leaches with boiling acid. The graphite residue retained > 50% of the long-lived fission products. Three successive leaches of fuel containing uranium and thorium recovered approximates 99% of both elements. Uranium recoveries by combustion in oxygen followed by dissolution of the ash hn nitric acid or fluorlde-catalyzed nitric acid are quantitative only when the fuel is not coated, does not contain Al/sub 2/O/sub 3/-coated fuel particles, and is free from impurities such as iron. During combustion up to 95% of the Ru-106 was volatilized from irradiated specimens. Recoveries, by leaching with 70% HNO/sub 3/, from fuel specimens containing Al/sub 2/O/sub 3/-coated fuel particles were greater than 99% when the specimens were ground finer than 200 mesh to ensure crushing of the fuel particles. (auth)
Thorium, Aluminum Oxides, Combustion, Residues, Efficiency, Ruthenium 106, Nitric Acid, Burnup, 620, Oxygen, Solutions, Reprocessing, Chemistry, Fuel Cans, Volatility, Fission Products, Graphite Moderator, Leaching, Boiling, Uranium, Graphite, Fuel Elements, Adsorption, Impurities
Thorium, Aluminum Oxides, Combustion, Residues, Efficiency, Ruthenium 106, Nitric Acid, Burnup, 620, Oxygen, Solutions, Reprocessing, Chemistry, Fuel Cans, Volatility, Fission Products, Graphite Moderator, Leaching, Boiling, Uranium, Graphite, Fuel Elements, Adsorption, Impurities
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