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Ceramic powder synthesis in supercritical fluids

Authors: Adkins, C. L. J.; Russick, E. M.; Cesarano, J.; Tadros, M. E.; Voigt, J. A.;

Ceramic powder synthesis in supercritical fluids

Abstract

Gas-phase processing plays an important role in the commercial production of a number of ceramic powders. These include titanium dioxide, carbon black, zinc oxide, and silicon dioxide. The total annual output of these materials is on the order of 2 million tons. The physical processes involved in gas-phase synthesis are typical of those involved in solution -phase synthesis: chemical reaction kinetics, mass transfer, nucleation, coagulation, and condensation. This report focuses on the work done under a Laboratory-Directed Research and Development (LDRD) project that explored the use of various high pressure techniques for ceramic powder synthesis. Under this project, two approaches were taken. First, a continuous flow, high pressure water reactor was built and studied for powder synthesis. And second, a supercritical carbon dioxide static reactor, which was used in conjunction with surfactants, was built and used to generate oxide powders.

Country
United States
Related Organizations
Keywords

Ceramics, Materials Working, Chemical Reaction Kinetics, Surfactants, Supercritical State, Nitrous Oxide, Test Facilities, Alkoxides, Process Control, Critical Temperature, Ammonia, Titanium Oxides, Chemical Reactors, Mass Transfer, Aerosols, Ethanol, 36 Materials Science, Water, Production, Powder Metallurgy, Carbon Dioxide, 540, 620, Bench-Scale Experiments, Nucleation, Powders, Critical Pressure

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
1
Average
Average
Average