We establish a connection between dependence structures and subclasses of distortion riskmetrics under which the latter are additive. A new notion of positive dependence, called partial comonotonicity, is developed, which nests the existing concepts of comonotonicity and single-point concentration. For two random variables, being comonotonic with a third one does not imply that they are comonotonic; instead, this defines an instance of partial comonotonicity. Any specific instance of partial comonotonicity uniquely characterizes a class of distortion riskmetrics through additivity under this dependence structure. An implication of this result is the characterization of the Expected Shortfall using single-point concentration.