Powered by OpenAIRE graph
Found an issue? Give us feedback
addClaim

A Practical Solution To Preparing A Sour Water For Injection

Authors: R.F. Weeter;

A Practical Solution To Preparing A Sour Water For Injection

Abstract

Introduction Degasification of hydrogen sulfide from sour San Andres source water in West Texas has increased the availability of water for a flood project in Midland County. The plant is treating water for Mobil Oil Co.'s flood project in the Pennsylvanian beds of the Pegasus field. About three years ago, it became apparent that supplies of water to be used in secondary recovery in the Permian Basin would soon become critically short and that use of available sour waters would be necessary in many floods yet to be started. It became further apparent that this sour water would have to be treated for removal of hydrogen sulfide before it could be used economically. Several methods of stripping H2S from water which were considered of limited potential success included: aeration with forced draft aerators; stripping the H2S with engine exhaust in a packed column; and stripping the H2S with exhaust gas produced by a submerged burner in a packed column. Finally, after studying all available methods, the following method was decided upon: Stripping the H2S with exhaust gas generated in an external vessel under carefully controlled conditions to produce an oxygen-free gas, using a bubble cap column of sufficient height to remove hydrogen sulfide to an acceptable residual, arbitrarily chosen as 1.5 ppm. However, this method had several drawbacks: The method had not been tried, even on a pilot scale. No equipment had been designed for this purpose. Design efficiencies had not been established. Time did not permit pilot plant operation. The bubble cap column was chosen since it is less subject to fouling than a packed column and, if fouled, is more readily cleaned. Some data were established by the author in a similar column using natural gas to strip oxygen from water. That column has operated successfully for approximately six years under operating conditions which place extreme design restrictions on the column, with resulting low efficiencies. COLUMN DESIGN Design of the column is based on Henry's law, which states that "the solubility of a gas in a liquid is directly proportional to the partial pressure [in atmospheres] of that gas in the surrounding atmosphere at a given temperature." Thus, if the partial pressure of H2S in the atmosphere surrounding the water approaches zero and if, at the same time, the H2S is given sufficient opportunity to escape from the water, the dissolved H2S will also approach zero. It is obvious that countercurrent stripping is ideal for obtaining these conditions. Design of the column trays was made using published data and the following criteria: Capacity = 13,000 BWPD Riser velocity = 10 ft/sec Tower diameter = 4 ft 1D Weir length = 3 ft Weir height = 4 in. Available gas pressure = 5 psig Since no samples of water from supply wells were available for the design, the following assumptions were made: Minimum operating temperature, 68 F Operating pressure, Atmospheric H2S content of water, 170 ppm Tray efficiency, 7 per cent pH of water, 6.0 Sulfides which are H2S, 86 per cent Gas/water ratio, 66. 7 scf/bbl

Related Organizations
  • BIP!
    Impact byBIP!
    selected citations
    These citations are derived from selected sources.
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    0
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Average
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Average
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Average
Powered by OpenAIRE graph
Found an issue? Give us feedback
selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
Average
Upload OA version
Are you the author of this publication? Upload your Open Access version to Zenodo!
It’s fast and easy, just two clicks!