Radiometric vicarious calibration of ocean color (OC) satellite sensors is carried out through the full sunlight path radiative transfer (RT) simulations of the coupled ocean-atmosphere system based on the aerosol and water-leaving radiance data from AERONET-OC sites for the visible and near-infrared (NIR) bands. Quantitative evaluation of the potential of such approach for achieving the radiometric accuracies of OC satellite sensors is made by means of direct comparisons between simulated and satellite measured top of atmosphere (TOA) radiances. Very high correlations (R ≥ 0.96 for all visible channels) are achieved for the Visible Infrared Imaging Radiometer Suite (VIIRS) sensor when this approach is applied with the data from the LISCO and WaveCIS AERONET-OC sites. Vicarious calibration gain factors derived with this approach are highly consistent, with comparisons between the two sites exhibiting around 0.5% discrepancy in the blue and green parts of the spectrum, while their average temporal variability is also within 0.28% - 1.23% permitting the approach to be used, at this stage, for verification of sensor calibration performance.