Transformation of a marine toxic polyether, okadaic acid.

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1988 English Publisher:Oxford University Press (OUP)Journal:Agricultural and Biological Chemistry, volume 52, pages 975-981 (issn: 0002-1369, eissn: 1881-1280,

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Authors: Yoshiyasu Ichikawa; Minoru Isobe; Toshio Goto;

doi: 10.1271/bbb1961.52.975 , 10.1080/00021369.1988.10868760

Transformation of a marine toxic polyether, okadaic acid.

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Abstract

Natural okadaic acid 1 was transformed into the 7, 24, 27-tri-0-benzyl-l, 2-acetonide derivative (4) in a 66% overall yidd. The corresponding synthetic derivative (4) was identified with this authentic sample.

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