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Chemical and Pharmaceutical Bulletin
Article . 1992 . Peer-reviewed
Data sources: Crossref
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Indonesian Medicinal Plants. V. Chemical Structures of Calotroposides C, D, E, F, and G, Five Additional New Oxypregnane-Oligoglycosides from the Root of Calotropis gigantea (Asclepiadaceae).

Authors: SHIBUYA, Hirotaka; ZHANG, Ru-song; PARK, Jong Dae; BAEK, Nam In; TAKEDA, Yasuyuki; YOSHIKAWA, Masayuki; KITAGAWA, Isao;

Indonesian Medicinal Plants. V. Chemical Structures of Calotroposides C, D, E, F, and G, Five Additional New Oxypregnane-Oligoglycosides from the Root of Calotropis gigantea (Asclepiadaceae).

Abstract

Following the chemical characterization of calotroposides A (1) and B (2), five related oxypregnane-oligoglycosides named calotroposides C (3), D (4), E (5), F (6), and G (7) have benn additionally isolated from the root of Calotropis gigantea (Asclepiadaceae), an Indonesian medicinal plant. The chemical structures of the new calotroposides have been elucidated on the basis of chemical and physicochemical properties as 12-O-benzoyldeacetylmetaplexigenin 3-O-β-D-oleandropyranosyl(1→4)-β-D-oleandropyranosyl(1→4)-β-D-oleandropyranosyl(1→4)-β-D-cymaropyranosyl(1→4)-β-D-cymaropyranoside for 3, 12-O-benzoyllineolon 3-O-β-D-oleandropyranosyl(1→4)-β-D-oleandropyranosyl(1→4)-β-D-oleandropyranosyl(1→4)-β-D-cymaropyranosyl(1→4)-β-D-cymaropyranoside for 4, 12-O-benzoyldeacetylmetaplexigenin 3-O-β-D-oleandropyranosyl(1→4)-β-D-oleandropyranosyl(1→4)-β-D-cymaropyranosyl(1→4)-β-D-cymaropyranoside for 5, 12-O-benzoyllineolon 3-O-β-D-oleandropyranosyl(1→4)-β-D-oleandropyranosyl(1→4)-β-D-cymaropyranosyl(1→4)-β-D-cymaropyranoside for 6, and 12-O-benzoyllineolon 3-O-β-D-oleandropyranosyl(1→4)-β-D-cymaropyranosyl(1→4)-β-D-cymaropyranoside for 7.

Related Organizations
Keywords

Asclepiadaceae, calotroposide, Calotropis gigantea, cymarose, oleandrose, oxypregnane-oligoglycoside, Indonesian medicinal plant

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    popularity
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    influence
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    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
26
Average
Top 10%
Average
gold