Far-Wing Excitation Spectra of the Hg 6s6p 3P0 – 6s7s 3S1 Inter-Excited-State Transitions Broadened by Ar and Ne

descriptionPublicationkeyboard_double_arrow_right Article 01 Sep 1996 English Publisher:Oxford University Press (OUP)Journal:Chemistry Letters, volume 25, pages 765-766 (issn: 0366-7022, eissn: 1348-0715,

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Authors: Kenji Ohmori; Kazuhiro Amano; Misaki Okunishi; Hisashi Chiba; Kiyoshi Ueda; Yukinori Sato;

doi: 10.1246/cl.1996.765

Far-Wing Excitation Spectra of the Hg 6s6p 3P0 – 6s7s 3S1 Inter-Excited-State Transitions Broadened by Ar and Ne

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Abstract

Abstract We have measured the laser-excitation spectra of the Hg–Ar and Hg–Ne collisional quasimolecules in the far wings of the Hg 6s6p 3P0 – 6s7s 3S1 inter-excited-state transitions broadened by Ar and Ne. The simulation of the spectrum, based on an uniform-semiclassical treatment for the free-free Franck-Condon factor, has been carried out for the Hg–Ar system in order to estimate the potential curves for the E31 and a 30− states of the quasimolecule.

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