Analysis of the Infrared Spectrum of RbCl Vapor

descriptionPublicationkeyboard_double_arrow_right Article 01 Feb 2000 English Publisher:Oxford University Press (OUP)Journal:Bulletin of the Chemical Society of Japan, volume 73, pages 321-327 (issn: 0009-2673, eissn: 1348-0634,

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Authors: John F Ogilvie; Hiromichi Uehara; Koui Horiai;

doi: 10.1246/bcsj.73.321

Analysis of the Infrared Spectrum of RbCl Vapor

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Abstract

Abstract With laser diodes we measured spectra of RbCl vapor near 1000 K in absorption in a region 43800—46400 m-1 and assigned vibration-rotational transitions, 226 of 85Rb35Cl up to ν′ = 9 and J′ = 160, 158 transitions of 85Rb37Cl and 125 of 87Rb35Cl, all with Δν = 2. We made a global fit of these 509 new data plus 28 published pure rotational transitions. Of eight evaluated parameters, six are adjusted, pertaining to a function for potential energy, and two are constrained, pertaining to nonadiabatic rotational effects; these parameters suffice to reproduce these data generally within uncertainties of their measurement. Comparison is made with corresponding spectral parameters of HCl, LiCl, NaCl and KCl.

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