AbstractIn this paper, we obtain a Bernstein-type concentration inequality and McDiarmid’s inequality under upper probabilities for exponential independent random variables. Compared with the classical result, our inequalities are investigated under a family of probability measures, rather than one probability measure. As applications, the convergence rates of the law of large numbers and the Marcinkiewicz–Zygmund-type law of large numbers about the random variables in upper expectation spaces are obtained.