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Phase Relationships in the Calcium Chloride – Calcium Carbide System

descriptionPublicationkeyboard_double_arrow_right Article 15 Mar 1972Publisher:Canadian Science PublishingJournal:Canadian Journal of Chemistry, volume 50, pages 839-843 (issn: 0008-4042, eissn: 1480-3291,

Authors: D. R. Morris; J. F. Maillot;

doi: 10.1139/v72-131

Phase Relationships in the Calcium Chloride – Calcium Carbide System

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Abstract

The system calcium chloride – calcium carbide has been examined by thermal analysis. The depression of the freezing point of CaCl2 by CaC2 is ideal. The system is a eutectic one, with a eutectic point at 90 mol% CaCl2 at 740 °C. Carbon is believed to be present in the electrolyte as the so called acetylide ion [Formula: see text] The melting point of pure CaCl2 was found to be 775.2 ± 0.6 °C.

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