Matrix Elements for Many-Electron Atoms: Electrostatic Interaction Energies for One-Open-Shell Configurations

descriptionPublicationkeyboard_double_arrow_right Article 01 Feb 1974 English Publisher:Canadian Science PublishingJournal:Canadian Journal of Physics, volume 52, pages 238-240 (issn: 0008-4204, eissn: 1208-6045,

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Authors: J. Karwowski; S. Fraga;

doi: 10.1139/p74-033

Matrix Elements for Many-Electron Atoms: Electrostatic Interaction Energies for One-Open-Shell Configurations

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Abstract

The matrix elements of the electrostatic interaction have been determined and tabulated, in terms of Slater–Condon integrals or Racah parameters, for the states arising from pN, dN, fN, and gN configurations; in particular, the results for gN configurations have never been determined before. The effect of the interaction between states of the same symmetry and multiplicity, arising from a given configuration, is exemplified with numerical results for Pr, 4f36s2.

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