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HAL-ENS-LYON
Article . 2022
Data sources: HAL-ENS-LYON
Journal of Rheology
Article . 2021 . Peer-reviewed
Data sources: Crossref
https://dx.doi.org/10.48550/ar...
Article . 2021
License: CC BY NC ND
Data sources: Datacite
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Shear-induced memory effects in boehmite gels

Authors: Sudreau, Iana; Manneville, Sébastien; Servel, Marion; Divoux, Thibaut;

Shear-induced memory effects in boehmite gels

Abstract

Colloidal gels are formed by the aggregation of Brownian particles into clusters that are, in turn, part of a space-spanning percolated network. In practice, the microstructure of colloidal gels, which dictates their mechanical properties, strongly depends on the particle concentration and on the nature of their interactions. Yet another critical control parameter is the shear history experienced by the sample, which controls the size and density of the cluster population, via particle aggregation, cluster breakup, and restructuring. Here, we investigate the impact of shear history on acid-induced gels of boehmite, an aluminum oxide. We show that following a primary gelation, these gels display a dual response depending on the shear rate γ˙p used to rejuvenate their microstructure. We identify a critical shear rate γ˙c, above which boehmite gels display a gel-like viscoelastic spectrum upon flow cessation, similar to that obtained following the primary gelation. However, upon flow cessation after shear rejuvenation below γ˙c, boehmite gels display a glassylike viscoelastic spectrum together with enhanced elastic properties. Moreover, the nonlinear rheological properties of boehmite gels also differ on both sides of γ˙c: weak gels obtained after rejuvenation at γ˙p>γ˙c show a yield strain that is constant, independent of γ˙p, whereas strong gels obtained with γ˙p<γ˙c display a yield strain that significantly increases with γ˙p. Our results can be interpreted in light of the literature on shear-induced anisotropy, which accounts for the reinforced elastic properties at γ˙p<γ˙c, while we rationalize the critical shear rate γ˙c in terms of a dimensionless quantity, the Mason number, comparing the ratio of the strength of the shear flow with the interparticle bond force.

Country
France
Keywords

[SDE] Environmental Sciences, Condensed Matter - Materials Science, Elasticity Fluid, Flocculation, Materials Science (cond-mat.mtrl-sci), FOS: Physical sciences, Viscoelastic Properties, Physics - Applied Physics, Applied Physics (physics.app-ph), Condensed Matter - Soft Condensed Matter, Dimensional analysis, Elasticity, Fluid flows, Colloidal systems, [CHIM] Chemical Sciences, Soft Condensed Matter (cond-mat.soft), Rheological properties, Gels

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    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    19
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 10%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Average
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 10%
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
19
Top 10%
Average
Top 10%
Green
bronze