Ways are suggested in which recent advancements in the fabrication of ultrasmooth, low scatter flow-polished mirror substrates and high-quality multilayer and interference film coatings can be used to create novel optical instruments for observing linear-polarization effects in the outer solar atmosphere. Attention is given to the observational parameters of all-reflective FUV/EUV imaging polarimeters; such a coronagraph/polarimeter, operating at Ly-alpha, could yield the first measurements of coronal vector magnetic fields.