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Hexakis(dimethyl sulfoxide)nickel(II) dinitrate dimethyl sulfoxide disolvate

descriptionPublicationkeyboard_double_arrow_right Article 10 Oct 2001 United Kingdom Publisher:International Union of Crystallography (IUCr)Journal:Acta Crystallographica Section E Structure Reports Online, volume 57, pages m556-m557 (eissn: 1600-5368,

Authors: Blake, AJ; Felloni, M; Hubberstey, P; Schroder, Martin; Wilson, C;

doi: 10.1107/s1600536801016403

Hexakis(dimethyl sulfoxide)nickel(II) dinitrate dimethyl sulfoxide disolvate

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Abstract

The title compound, [Ni(C2H6OS)6](NO3)2·2C2H6OS, comprises centrosymmetric [Ni(dmso)6]2+ cations, nitrate anions and non-coordinated dimethyl sulfoxide solvent molecules. The octahedral geometry of the cation is very regular, with Ni—O interatomic distances and O—Ni—O interatomic angles falling within narrow ranges 2.0485 (9)–2.0665 (9) A and 89.12 (4)–93.27 (4)°, respectively. Two weak C—H⋯O hydrogen-bonding contacts link cations and anions to form a chain which lies along the [111] direction.

Country

United Kingdom

Related Organizations

Nottingham Trent University
United Kingdom
University of Salford
United Kingdom

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