Compounds of glycine with metal sulfates and thiosulfates: glycine cobalt sulfate pentahydrate, glycine sodium thiosulfate dihydrate and glycine potassium thiosulfate
Copyright policy )Compounds of glycine with metal sulfates and thiosulfates: glycine cobalt sulfate pentahydrate, glycine sodium thiosulfate dihydrate and glycine potassium thiosulfate
In the crystal structures of the title compounds, hexaaquacobalt(II) tetraaquadiglycinatocobalt(II) bis(sulfate), [Co(H2O)6][Co(C2H5NO2)2(H2O)4](SO4)2, (I), poly[diaqua-mu3-glycinato-di-mu4-thiosulfato-tetrasodium(I)], [Na4(C2H5NO2)(S2O3)2(H2O)2]n, (II), and poly[mu2-glycinato-mu4-thiosulfato-dipotassium(I)], [K2(C2H5NO2)(S2O3)]n, (III), all atoms are located on general positions, except the Co atoms in (I), which are located on inversion centres. In (I), hydrogen bonds play an important role, while the alkali thiosulfate compounds are characterized by three-dimensional frameworks of polyhedra. Relations to other compounds of glycine and metal sulfates are commented on.
- University of Vienna Austria
- University of Cologne Germany
105113 Kristallographie, Molecular Structure, Glycine, Thiosulfates, 105113 Crystallography, Hydrogen Bonding, Cobalt, Crystallography, X-Ray
105113 Kristallographie, Molecular Structure, Glycine, Thiosulfates, 105113 Crystallography, Hydrogen Bonding, Cobalt, Crystallography, X-Ray
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