We consider here chiral symmetry breaking through nontrivial vacuum structure with quark antiquark condensates. We then relate the condensate function to the wave function of pion as a Goldstone mode. This simultaneously yields the pion also as a quark antiquark bound state as a localised zero mode in vacuum. We illustrate the above with Nambu Jona-Lasinio model to calculate different pionic properties in terms of the vacuum structure for breaking of exact or approximate chiral symmetry, as well as the condensate fluctuations giving rise to $σ$ mesons.

latex, revtex, 16 pages