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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao https://doi.org/10.1...arrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
https://doi.org/10.1103/physre...
Article . 1999 . Peer-reviewed
License: APS Licenses for Journal Article Re-use
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Theory of the martensitic phase transformations in lithium and sodium

Authors: O. Blaschko; V. Dmitriev; G. Krexner; P. Tolédano;

Theory of the martensitic phase transformations in lithium and sodium

Abstract

A phenomenological model is proposed which describes the static and dynamical properties observed in connection with the martensitic transformations in lithium and sodium. The martensite structure is shown to result from a coupling between the mechanisms associated with the $\mathrm{bcc}\ensuremath{-}9R,$ bcc-hcp, and bcc-fcc transformations. These mechanisms are expressed in terms of primary displacive order parameters, involving definite critical shifts, and of additional spontaneous symmetry breaking strains. The theoretical phase diagrams in which the bcc and martensite phases are inserted are worked out. They contain regions of stability for intermediate phases. The existence or absence of softening of the ${\ensuremath{\Sigma}}_{4}$ phonon branch with temperature, as a precursor effect to the transformation, is shown to depend on the distance of the experimental thermodynamic path to the corresponding intermediate phase. The nonlocalized character of the softening region on the ${\ensuremath{\Sigma}}_{4}$ branch reflects the coupling of the different structural mechanisms involved in the transformation. The irrational values found for the wave vectors at the phonon dips are interpreted by an implicitly incommensurate character of the transformation, which originates from the distinct coherency stresses between the potentially stable close-packed structures and the bcc matrix. It results in the creation of strain fields acting inhomogeneously on the effective transformation order parameter, and explains the observed incubation times and response of the crystals to elastic and plastic deformations. These properties are shown to be consistent with a nucleation process on elastic defects which is activated only close to the transformation.

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Powered by OpenAIRE graph
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
37
Top 10%
Top 10%
Top 10%
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