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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao https://doi.org/10.1...arrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
https://doi.org/10.1103/physre...
Article . 1996 . Peer-reviewed
License: APS Licenses for Journal Article Re-use
Data sources: Crossref
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Adsorption strains in porous silicon

Authors: , Dolino; , Bellet; , Faivre;

Adsorption strains in porous silicon

Abstract

X-ray-diffraction observations of strains induced by vapor adsorption are reported for porous silicon single-crystal samples. Two types of porous silicon ($p$ and ${p}^{+}$) with very different pore structure are investigated. A low-pressure contraction is observed in $p$-type samples with spherical pores of about 3-nm diameter. In ${p}^{+}$-type samples, where the pores are cylindrical with a larger diameter of about 10 nm, a minimum of the lattice parameter versus the vapor pressure is observed when capillary condensation occurs with a distinct hysteresis between increasing and decreasing vapor pressure. Finally, an expansion is observed for complete wetting. These results are discussed for the different pressure ranges in relation to previous experimental and theoretical studies on adsorption strains. The analogous features observed for very different materials could have a common origin. The expansion is easily explained by the decrease of surface energy due to adsorption and wetting. It appears that the low-pressure contraction is partially related to the attractive van der Waals interactions induced by vapor adsorption in nanometer-size cavities. The softening of the elastic constants observed in porous silicon is discussed in order to explain the magnitude of the observed strains.

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Powered by OpenAIRE graph
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
112
Top 10%
Top 1%
Top 10%
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