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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao https://doi.org/10.1...arrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
https://doi.org/10.1103/physre...
Article . 1994 . Peer-reviewed
License: APS Licenses for Journal Article Re-use
Data sources: Crossref
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Relativistic effects in the x-ray-absorption fine structure

Authors: , Tyson;

Relativistic effects in the x-ray-absorption fine structure

Abstract

A relativistic model for the extended x-ray-absorption fine structure, in which the energy loss of the emitted photoelectron is accounted for by using a complex energy-dependent exchange-correlation potential, has been developed. Relativistic curved-wave single-, double-, and triple-scattering formulas for excitation from any core hole have been found. The dominant single-scattering signal has been computed for the first shell at the ${\mathit{L}}_{2}$ and ${\mathit{L}}_{3}$ edges of Th (Z=90), Pt (Z=78), and Eu (Z=63) and at the K edge of Sr (Z=38) using this model. Comparisons of the relativistic scattering amplitudes of the Dirac model with the current standard Schr\"odinger curved-wave model reveal that the latter deviates from the more exact Dirac model by 20% above 240 eV for Th, by 15% above 240 eV for Pt, and by 10% above 140 eV for Eu. For lower energies, the deviations are as much as two times larger. Differences between the Dirac model ${\mathit{L}}_{2}$- and ${\mathit{L}}_{3}$-edge amplitudes occur below 240 eV for Th and Pt with values of 2% and 6%, respectively. For Eu, this difference diminishes to 4% and occurs only below 140 eV. In the case of the K edge of Sr, the Schr\"odinger single-scattering amplitude differs from the Dirac amplitude by 5% for energies above 95 eV. The spin dependence of the generalized Ramsauer-Townsend effect is also exhibited.

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Powered by OpenAIRE graph
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
15
Top 10%
Top 10%
Top 10%
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