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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao https://doi.org/10.1...arrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
https://doi.org/10.1103/physre...
Article . 1990 . Peer-reviewed
License: APS Licenses for Journal Article Re-use
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Valence state for bismuth in the superconducting bismuth cuprates

Authors: , Retoux; , Studer; , Michel; , Raveau; , Fontaine; , Dartyge;

Valence state for bismuth in the superconducting bismuth cuprates

Abstract

X-ray-absorption near-edge spectra (XANES) of high-${T}_{c}$ bismuth superconductors (2:2:0:1, 2:2:1:2, and 2:2:2:3) have been recorded at the Bi ${L}_{\mathrm{III}}$, ${L}_{\mathrm{I}}$, and Cu K edges. With respect to the reference ${\mathrm{Bi}}_{2}$${\mathrm{O}}_{3}$ [Bi(iii) valence state], edge shifts towards low energies have been found in the spectra of all the superconducting cuprates at the Bi ${L}_{\mathrm{III}}$ edge. This has been interpreted in terms of a reduced bismuth valency smaller than Bi (iii). This result is a characteristic of the superconducting intergrowths, since other layer compounds with Bi cations in similar environments, ${\mathrm{Bi}}_{2}$${\mathrm{SrNb}}_{2}$${\mathrm{O}}_{9}$ and ${\mathrm{Bi}}_{2}$${\mathrm{Sr}}_{2}$${\mathrm{CaFe}}_{2}$${\mathrm{O}}_{9}$, do not present any shift with respect to ${\mathrm{Bi}}_{2}$${\mathrm{O}}_{3}$. The copper formal valency has been deduced either from charge-balance considerations assuming a well-known oxygen stoichiometry or edge shifts at the copper K edge. High copper valencies have been found, especially in the 2:2:0:1 compound, but again, as was observed before in thallium and lead-substituted thallium cuprates, critical temperatures increase when the copper valency decreases, i.e., when the number of holes per copper in an oxygen-like p band decreases, provided this number stands above a critical value estimated previously to be 0.17.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
108
Top 10%
Top 1%
Top 1%
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