
pmid: 9993624
We report self-consistent surface electronic-structure calculations for metals across the lanthanide series. We have used the self-consistent-field linear muffin-tin orbital method with the atomic-sphere approximation in a supercell'' geometry. The calculations provide values of the surface core-level shifts (SCLS) on the (0001) face for all the hcp lanthanides, which compare well with experimental results. We have confirmed that the trend of the increasing SCLS across the series can be explained by a monotonic decrease in the valence--{ital d}-electron count.
| selected citations These citations are derived from selected sources. This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically). | 29 | |
| popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network. | Average | |
| influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically). | Top 10% | |
| impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network. | Top 10% |
