A series of entropies, approaching the order-q Renyi's entropies when the length of orbits tends to infinity, is considered. Their scaling form is determined for chaotic one-dimensional maps. For the characteristic relaxation time a general expression is derived, and it is shown to be closely related to the eigenvalues of a generalized Frobenius-Perron operator. The case of intermittent maps is also considered, and the spectrum of relaxation time is found to reflect the phase transition at q = 1. Results of numerical experiments are also presented.