
The partition function of the classical imperfect gas is approximated by means of a generalized cell model in which the number of particles in a cell is taken as the statistical variable. The limiting free energy per particle exhibits critical phenomena, and, for temperatures less than the critical temperature, the $p\ensuremath{-}v$ isotherm is a nonanalytic function of $v$ consisting of three pieces. These properties depend only on the interparticle potential energy having the general features usually assigned to it. However, the condensation pressure is not constant, and, for temperatures sufficiently low, the isotherm shows thermodynamic instability. The model allows the calculation of the limiting free energy per particle for all values of the temperature and specific volume.
classical thermodynamics, heat transfer
classical thermodynamics, heat transfer
| selected citations These citations are derived from selected sources. This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically). | 6 | |
| popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network. | Average | |
| influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically). | Top 10% | |
| impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network. | Average |
