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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao https://doi.org/10.1...arrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
https://doi.org/10.1103/physre...
Article . 1938 . Peer-reviewed
License: APS Licenses for Journal Article Re-use
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Quadrupole-Quadrupole Interatomic Forces

Authors: Julian K. Knipp;

Quadrupole-Quadrupole Interatomic Forces

Abstract

Atoms the normal states of which are not $S$ states experience quadrupole-quadrupole repulsive and attractive forces which vary as the inverse fifth power of the separation distance. At large distances, exchange being negligible, the expression for the interaction energy contains as factors two atomic coefficients and a root of a secular equation determined by the molecular state of the system. For a given atom the coefficient is determined by the nature of its lowest level. If one uses the Hartree-Fock approximation, it is proportional to the average of the square of the radial atomic distance for those electrons with orbital angular momentum not in complete shells. Atomic coefficients have been calculated for most of the atoms of the periodic table having incomplete $p$ and $d$ shells and the secular equations have been solved for a number of cases. At distances of twice the sum of the atomic radii, diatomic molecules resulting from the combination of such atoms of the first row of the periodic table have quadrupole-quadrupole energies of a few tenths of a volt, such energies becoming rapidly larger for smaller distances because of the inverse fifth power dependence.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
59
Top 10%
Top 1%
Top 10%
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