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https://doi.org/10.1103/physre...
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The Entropy and Thermodynamic Potentials of Real Gases and Mixtures of Real Gases and a Mass Action Law for Chemical Reaction Between Real Gases: II. Integrated Equations

Authors: James A. Beattie;

The Entropy and Thermodynamic Potentials of Real Gases and Mixtures of Real Gases and a Mass Action Law for Chemical Reaction Between Real Gases: II. Integrated Equations

Abstract

The general thermodynamic equations derived in the first paper are integrated by means of a new equation of state for gas mixtures. Thus the energy, heat content, entropy and thermodynamic potentials ${F}_{V,T}$ and ${F}_{p,T}$ of a mixture of real gases, and the chemical potential and fugacity of a gas in a mixture are expressed as integrated functions of $V, T, {n}_{1}, {n}_{2}, \ensuremath{\cdots}$, and the constants of the equation of state of the pure gases composing the mixture. The expression for the thermodynamic potential ${F}_{V,T}$ is a fundamental equation in the Gibbs sense. A mass action law for reactions between real gases is given, the "mass action constant" ${K}_{p}$ being expressed in terms of the variables $V, T, {x}_{1}, {x}_{2}, \ensuremath{\cdots}$, ${\ensuremath{\nu}}_{1}, {\ensuremath{\nu}}_{2}, \ensuremath{\cdots}$, and the equation of state constants of the pure gases composing the equilibrium mixture. The determination of the values of the various integration constants are discussed for the following cases: (a) non-isothermal and (b) isothermal variations in the state of a system composed of gases which react chemically, (c) non-isothermal and (d) isothermal variations in the state of a system composed of nonreacting gases.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
9
Average
Top 10%
Top 10%
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