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Philosophical Transactions of the Royal Society A Mathematical Physical and Engineering Sciences
Article . 2010 . Peer-reviewed
License: Royal Society Data Sharing and Accessibility
Data sources: Crossref
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Catalyst supports for polymer electrolyte fuel cells

Authors: Subban, Chinmayee; Zhou, Qin; Leonard, Brian; Ranjan, Chinmoy; Edvenson, Heather M.; DiSalvo, F. J.; Munie, Semeret; +1 Authors

Catalyst supports for polymer electrolyte fuel cells

Abstract

A major challenge in obtaining long-term durability in fuel cells is to discover catalyst supports that do not corrode, or corrode much more slowly than the current carbon blacks used in today’s polymer electrolyte membrane fuel cells. Such materials must be sufficiently stable at low pH (acidic conditions) and high potential, in contact with the polymer membrane and under exposure to hydrogen gas and oxygen at temperatures up to perhaps 120°C. Here, we report the initial discovery of a promising class of doped oxide materials for this purpose: Ti 1− x M x O 2 , where M=a variety of transition metals. Specifically, we show that Ti 0.7 W 0.3 O 2 is electrochemically inert over the appropriate potential range. Although the process is not yet optimized, when Pt nanoparticles are deposited on this oxide, electrochemical experiments show that hydrogen is oxidized and oxygen reduced at rates comparable to those seen using a commercial Pt on carbon black support.

Country
United States
Related Organizations
Keywords

Titanium, Conductivity, Conservation of Natural Resources, Energy-Generating Resources, Polymers, Catalyst supports, Oxides, Hydrogen-Ion Concentration, Electric Power Supplies, Electricity, X-Ray Diffraction, Biofuels, Materials Testing, Electrochemistry, Nanoparticles, Nanotechnology, Fuel cells, Electrodes, Platinum

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    popularity
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    influence
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
22
Top 10%
Top 10%
Top 10%
bronze